SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.055M) Wed Feb 24 14:42:30 2021 No. of days remaining = 365 Empirical Formula: V4 Cl24 K8 = 36 atoms MERS=(1,1,1) UHF CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Potassium hexachlorovanadate(iv) (K2VCl6) (ICSD 1712440) GRADIENTS WERE INITIALLY ACCEPTABLY SMALL SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -1549.62592 KCAL/MOL = -6483.63486 KJ/MOL H.o.F. per unit cell = -387.40648 KCAL, for 4 unit cells, unit cell = V1 Cl6 K2 TOTAL ENERGY = -7009.20274 EV ELECTRONIC ENERGY = -16057035.17625 EV CORE-CORE REPULSION = 16050025.97351 EV VOLUME OF UNIT CELL = 879.157 CUBIC ANGSTROMS DENSITY = 2.583 GRAMS/CC A = 9.584 ANGSTROMS B = 9.578 ANGSTROMS C = 9.577 ANGSTROMS ALPHA = 89.857 DEGREES BETA = 89.928 DEGREES GAMMA = 89.894 DEGREES GRADIENT NORM = 3.73017 = 0.62170 PER ATOM (SZ) = 0.000000 (S**2) = 2.016309 NO. OF ALPHA ELECTRONS = 98 NO. OF BETA ELECTRONS = 98 IONIZATION POTENTIAL = 8.865377 EV ALPHA SOMO LUMO (EV) = -8.865 -2.244 BETA SOMO LUMO (EV) = -8.870 -2.248 MOLECULAR WEIGHT = 1367.4244 Pressure required to constrain translation vectors Tv( 37) Pressure: 0.05 GPa Tv( 38) Pressure: 0.04 GPa Tv( 39) Pressure: 0.01 GPa SCF CALCULATIONS = 1 WALL-CLOCK TIME = 52.785 SECONDS COMPUTATION TIME = 51.927 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,1,1) UHF CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Potassium hexachlorovanadate(iv) (K2VCl6) (ICSD 1712440) V -0.02912464 +1 -0.02287096 +1 0.03108260 +1 Cl -2.31683790 +1 -0.02230592 +1 0.02906441 +1 Cl -0.02677228 +1 2.26461746 +1 0.03158451 +1 Cl -0.03051851 +1 -2.31197362 +1 0.02506013 +1 Cl -0.02814368 +1 -0.02166741 +1 -2.25529836 +1 Cl -0.02985098 +1 -0.02927567 +1 2.31844022 +1 Cl 2.24446967 +1 -4.83008358 +1 4.82331701 +1 Cl -2.32691299 +1 -4.82571395 +1 4.82538147 +1 Cl -0.04027313 +1 -2.54164096 +1 4.82986969 +1 Cl -0.04431911 +1 -7.11869966 +1 4.82563475 +1 Cl -0.03859941 +1 -4.82601167 +1 2.53461509 +1 Cl -0.04430664 +1 -4.83281497 +1 7.10995936 +1 Cl -2.54166474 +1 -4.82557756 +1 0.02900151 +1 Cl -7.11729695 +1 -4.81944214 +1 0.03385630 +1 Cl -4.82921534 +1 -2.53739651 +1 0.03271739 +1 Cl -4.83224009 +1 -7.11354788 +1 0.03358186 +1 Cl -4.82904954 +1 -4.82108935 +1 -2.26112368 +1 Cl -4.82736705 +1 -4.82200850 +1 2.31699333 +1 Cl -2.53576801 +1 -0.03236081 +1 4.83047918 +1 Cl -7.11256803 +1 -0.02935058 +1 4.82708209 +1 Cl -4.82323738 +1 2.25298945 +1 4.82869728 +1 Cl -4.82688973 +1 -2.32265912 +1 4.82965353 +1 Cl -4.82692591 +1 -0.03642046 +1 2.54058041 +1 Cl -4.82769130 +1 -0.02977958 +1 7.11731727 +1 K 2.36147543 +1 2.36940529 +1 -2.36732657 +1 K -2.42813317 +1 -2.42425609 +1 2.42264208 +1 K 2.35279054 +1 -2.43019388 +1 2.42557933 +1 K -2.41658490 +1 2.37231760 +1 -2.36095508 +1 K -2.42468335 +1 -2.42127249 +1 -2.35787492 +1 K 2.36540958 +1 2.37067429 +1 2.41921880 +1 K -2.42740181 +1 2.36301520 +1 2.42278623 +1 K 2.35993711 +1 -2.41679892 +1 -2.36908624 +1 V -0.04153817 +1 -4.83021137 +1 4.82305262 +1 V -4.82982012 +1 -4.82550010 +1 0.02756800 +1 V -4.82442322 +1 -0.03474793 +1 4.82945682 +1 Cl 2.25733779 +1 -0.02404475 +1 0.03435444 +1 Tv 0.01084133 +1 9.58376556 +1 -0.00698684 +1 Tv 0.00991363 +1 0.01074779 +1 -9.57846917 +1 Tv 9.57713183 +1 0.00117830 +1 -0.01394086 +1